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31.

For the reaction

$2NO_{2}(_{g})\rightleftharpoons2NO_{(g)} +O_{2}(_{g})$

(Kc = 1.8 x 10-6 at 184°C) (R = 0.0831kJ/mol.K)

When Kp and Kc are compared at 184°C, it is found that


A) Whether $K_{p}$ is greater than, less than or equal to $K_{c}$ depends upon the total gas pressure

B) $K_{p}= K_{c}$

C) $K_{p}$ is less than $K_{c}$

D) $K_{p}$ is greater than $K_{c}$



32.

The exothermic formation of ClF3 is represented by the equation:

 2352021298_11036427.png

Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and ClF3?


A) Adding $F_{2}$

B) Increasing the volume of the container

C) Removing $Cl_{2}$

D) Increasing the temperature



33.

Schottky defect in crystals is observed when


A) unequal number of cations and anions are missing from the lattice

B) equal number of cations and anions are missing from the lattice

C) an ion leaves its normal site and occupies an interstitial site

D) density of the crystal is increased



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